7646-79-9 Kinetics of the Thermal Intramolecular Redox Reaction of Pentaamminenitrosylcobalt(III) Chloride in the Solid State

The kinetics of the thermal intramolecular redox reaction between NO- and Co(III) in Cl2 has been studied by means of thermogravimetric and thermomagnetic analyses.The reaction is found to follow the first-order equation, with ΔH(excit.) = 129 +/- 6 kJ mol-1 and ΔS(excit.) = 14 +/- 16 J mol-1 K-1.These results are compared with the kinetics of other nitrosylcobalt(III) and hexaamminecobalt(III) complexes. https://www.lookchem.com/CASDataBase_7646-79-9.htm

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