7439-95-4 Microstructure and mechanical behavior of AZ91 Mg alloy processed by equal channel angular pressing

A fine-grained AZ91 alloy was prepared by equal channel angular pressing (ECAP). The evolution of the microstructure and the deformation behavior were investigated as a function of the number of ECAP passes. At room temperature the tensile strength of the ECA pressed specimens is higher than that of the initial state due to the grain refinement and the increase of the dislocation density during ECAP. Above 200 °C the ductility increases due to the increase of the relative fraction of c + a dislocations and also owing to the breakage of the rod-like Al12Mg17 precipitates during ECAP processing. https://www.lookchem.com/CASDataBase_7439-95-4.htm

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726-18-1 Electrophilic alkylations in neutral aqueous or alcoholic solutions

Acid-free Friedel-Crafts chemistry: A paradox? Nucleophilicity scales, based on reactions with benzhydrylium ions, show that many π systems are more nucleophilic than aqueous or alcoholic solutions that are generally employed as solvents for S N 1 reactions. Solvolytically generated carbocations can, therefore, be trapped by donor-substituted arenes and alkenes to form products of Friedel-Crafts-type reactions in neutral aqueous solutions (see scheme). https://www.lookchem.com/CASDataBase_726-18-1.htm
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102-82-9 Selective Synthesis of Secondary and Tertiary Amines by Reductive N-Alkylation of Nitriles and N-Alkylation of Amines and Ammonium Formate Catalyzed by Ruthenium Complex

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1023-17-2 Syntheses, structures, and catalytic activity in Friedel–Crafts acylations of substituted tetramethylcyclopentadienyl molybdenum carbonyl complexes

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