101-97-3 Metal-free hydroalkoxylation of ynesulfonamides with esters

An efficient metal-free hydroalkoxylation reaction of ynesulfonamides with esters under mild conditions is described. Under the catalysis of TMSOTf, various ynesulfonamides are transformed into the corresponding alkoxy-substituted enamides in high yields with complete regioselectivity and high to excellent stereoselectivity. https://www.lookchem.com/CASDataBase_101-97-3.htm

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