1003-31-2 DMF-catalysed thermal dehydration of aldoximes: A convenient access to functionalized aliphatic and aromatic nitriles

N,N-Dimethylformamide was found to act as solvent and catalyst in the dehydration of aldoximes to nitriles. The reaction required heating at 135°C and yields of nitriles were moderate to good. (Benzylideneaminooxy)formaldehyde was detected as an intermediate in one of the reactions. Georg Thieme Verlag Stuttgart. https://www.lookchem.com/CASDataBase_1003-31-2.htm

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